Transformasi biji jarak pagar (Jatropha curcas L.) menjadi biodiesel melalui transesterifikasi in situ
Abstract
Biodiesel is defined as mono-alkyl esters from transesterification reaction of triglycerides with alkyl alcohol. In situ transesterification is a method to produce biodiesel from oil sources of material by eliminating process steps of oil extraction and refining. The purpose of this research is to study the transformation process of Jatropha seeds into biodiesel by in situ transesterification on the 10 liters scale by studying the influence of reaction time, stirring speed and ratio methanol/hexane/material on the yield and quality of biodiesel. In situ transesterification of Jatropha seeds was carried out under the following process condition: the moisture content of Jatropha seeds were less than 2%, the particles size were ± 20 mesh and KOH concentration was 0.075 mol/L methanol. Operating condition of in situ transesterification was varied at 4 and 6 hours reaction time, 200 and 600 rpm stirring speed and ratio methanol/hexane/material (v/v/w) were 3:3:1, 4:2:1 and 5:1:1. Analysis of variance showed that reaction time, stirring speed and ratio methanol/hexane/material did not significantly affected the yield, acid value, saponification value, ester value, viscosity and ash content of biodiesel. The biodiesel yield was produced between 82.54-87.57%. The best biodiesel yield on all of treatments was 87.57% with condition treatment were reaction time of 6 hours, stirring speed 600 rpm and ratio methanol/hexane/material (v/v/w) of 4:2:1. Acid value, saponification value and ester value of biodiesel were 0.20-0.26 mg KOH/g, 185.49-194.30 mg KOH/g and 185.29-194.10 mg KOH/g respectively. Viscosity of biodiesel was 3.49-6.36 cSt. The ash content of biodiesel was 0%, but the condition treatment, were reaction time of 4 hours, stirring speed of 600 rpm and ratio methanol/hexane/material (v/v/w) of 5:1:1, had ash content of 0.007%. Jatropha cakes had total volatile matter content 1.80-3.64% and extracted material content 3.94-11.42%.
