Karakteristik Carboxymethyl Chitosan Dengan Variasi Konsentrasi NaOH

Abstract

Carboxymethyl chitosan is chitosan derivative product obtained from chemical modification. CMCh were made by alkalization process and carboxymethylation process. Factors that affect CMCh characteristics were excess sodium hydroxide in alkalization process, ratio between chitosan and monochloroacetic acid, and carboxymethylation temperature. The objectives of this research were to study the NaOH effect to CMCh characteristics, to learn process of making CMCh, to set the proper concentration of NaOH, and to analyze CMCh characteristics. CMCh yields were 110.72%-114.22%. CMCh pH value were 3.74-4.31. The optimum NaOH concentration to obtain the best CHCh was 10 M. Percentage of CMCh moisture content was 10.70%-11.42%. Ash content and nitrogen content of CMCh were 0.49%-0.50% and 4.52%-4.81%. CMCh viscousity was 8.25 cps. Percentage of CMCh solubility was 61.61%-91.50%. The different functional groups from chitosan which observed in CMCh were C=O group, CH group from alkene functional group, C−O group, and C−O−C group.