Membran Komposit Kitosan-Zeolit untuk Aplikasi Direct Methanol Fuel Cell

Abstract

Direct methanol fuel cell (DMFC) is a fuel cell that utilize methanol as the fuel source. The electrolyte membrane used in the DMFC system in this research was chitosan-zeolite composite membrane. The composite membrane was synthesized with chitosan-zeolite composition variation of 1:1, 1:2, 1:3, and 2:1. The membranes were analyzed by Fourier transform infrared spectrophotometer (FTIR) and scanning electron microscope, and for the specific gravity. Membrane performances were tested with methanol uptake, methanol permeability, conductivity, and potential difference in the DMFC system. The FTIR spectrum showed no formation of new functional groups inducating that the composite membrane was a result of physical mixing. Morphological analysis showed that the membrane was nonporous. Chitosan-zeolite 1:3 composite membrane had the highest specific gravity and methanol uptake, 1.4226 g/mL and 41.44%, respectively. The highest proton conductivity was showed by the 1:2 chitosanzeolite composite membrane, namely 7.2946× 10-7 S/cm. Based on this research results, chitosan-zeolite composite membrane can be applied in DMFC system.