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      Karakteristik Perekat Poliuretan Berbasis Lignin dengan Modifikasi Biopoliol untuk Kayu Lapis

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      Date
      2023-07-14
      Author
      Sapenti, Ajeng Dzakiyyah
      Sari, Rita Kartika
      Lubis, Muhammad Adly Rahandi
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      Abstract
      Perekat poliuretan berbasis lignin dengan modifikasi biopoliol dapat dijadikan substitusi perekat Urea Formaldehida (UF) untuk kayu lapis karena dapat digunakan sebagai perekat eksterior, lebih ramah lingkungan, dan tidak menghasilkan emisi formaldehida. Penelitian ini bertujuan untuk menganalisis pengaruh penambahan konsentrasi PVOH/Lignin terhadap karakteristik perekat dan kayu lapis. Perekat dibuat dengan mencampurkan Metilen Difenil Isosianat (MDI), poliol, Poly Vinyl Alcohol (PVOH), dan lignin kemudian diaplikasikan pada vinir dengan suhu kempa 120 ℃ selama 4 menit. Rendemen lignin yang diperoleh yaitu 36,17%. Semakin tinggi konsentrasi Lignin/PVOH maka kadar padatan semakin menurun sedangkan viskositas, kohesi, torsi, storage modulus, loss modulus, dan tan delta mengalami peningkatan. Pada analisis FTIR, gugus penanda terbentuknya ikatan uretan teridentifikasi pada perekat ataupun kayu lapis. Formula perekat poliuretan berbasis lignin F1, F2, dan F3 memenuhi nilai delaminasi, keteguhan rekat, dan kerusakan kayu berdasarkan SNI (01-5008.7-1999). Pada formula tersebut gugus -OH dari lignin ataupun dari kayu lapis dapat berikatan dengan gugus -NCO sehingga memiliki sifat kohesi dan sifat adhesi yang baik.
       
      Lignin-based polyurethane adhesive with bio polyol modification can be used as a substitute for Urea Formaldehyde (UF) adhesive for plywood because it can be used as an exterior adhesive, is more environmentally friendly, and does not produce formaldehyde emissions. This study aims to analyze the effect of adding PVOH/Lignin concentration on the characteristics of the adhesive and plywood. The adhesive is made by mixing Methylene Diphenyl Isocyanate (MDI), polyol, Poly Vinyl Alcohol (PVOH), and lignin, then applied to the veneer with a compression temperature of 120 ℃ for 4 minutes. The yield of lignin obtained was 36.17%. The higher the concentration of Lignin/PVOH, the solids content decreased, while the viscosity, cohesion, torque, storage modulus, loss modulus, and tan delta increased. FTIR analysis identified markers for forming urethane bonds in adhesives or plywood. The lignin-based polyurethane adhesive formulas F1, F2, and F3 comply with delamination, tensile shear strength, and wood failure values according to the Indonesia National Standard (SNI 01-5008.7-1999). In this formula, the -OH group from lignin or plywood can form bonds with the -NCO group, resulting in good cohesion and adhesion properties.
       
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      http://repository.ipb.ac.id/handle/123456789/121872
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      • UT - Forestry Products [2469]

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      Indonesia DSpace Group 
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